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Document Type |
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Article In Journal |
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Document Title |
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{5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1, 3-diyldinitrilo)-diethylidyne]diphenolato-k4 O,N,N′,O′} copper(II) monohydrate {5,5′-Dimethoxy-2,2′-[1,1′-(2,2-dimethylpropane-1, 3-diyldinitrilo)-diethylidyne]diphenolato-k4 O,N,N′,O′} copper(II) monohydrate |
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Subject |
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Chemistry |
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Document Language |
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English |
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Abstract |
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The tetra-dentate dianion in the title complex hydrate, [Cu(C 23H28N2O4)]·H2O, provides the CuII atom with a cis-N2O2 donor set. There is a significant twist from a regular square-planar geometry with the dihedral angle formed between the two six-membered CuOC3N chelate rings being 32.14 (8)°. The water molecule forms hydrogen bonds to each of the coordinating O atoms of a given complex molecule. Supra-molecular layers in the bc plane are formed in the crystal packing through C-H⋯O and C-H⋯π interactions. |
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ISSN |
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1600-5368 |
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Journal Name |
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Acta Crystallographica Section E: Structure Reports Online |
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Volume |
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67 |
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Issue Number |
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10 |
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Publishing Year |
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1432 AH
2011 AD |
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Article Type |
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Article |
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Added Date |
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Tuesday, December 6, 2011 |
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Researchers
| A Ghaemi | Ghaemi, A | Researcher | Doctorate | |
| S Rayati | Rayati, S | Researcher | Doctorate | |
| E Elahi | Elahi, E | Researcher | Doctorate | |
| Seik Weng Ng | Ng, Seik Weng | Researcher | Doctorate | seikweng@um.edu.my |
| E R T Tiekink | Tiekink, E R T | Researcher | Doctorate | edward.tiekink@gmail.com |
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