Document Details

Document Type : Article In Journal 
Document Title :
Hyperbranched Polymers by Type II Photoinitiated Self-Condensing Vinyl Polymerization
Hyperbranched Polymers by Type II Photoinitiated Self-Condensing Vinyl Polymerization
 
Document Language : English 
Abstract : Type II photoinitiated self-condensing vinyl polymerization for the preparation of hyperbranched polymers is explored using 2-hydroxyethyl methacrylate (HEMA) or 2-(dimethylamino) ethyl methacrylate (DMAEMA), and methyl methacrylate as hydrogen donating inimers and comonomer, respectively, in the presence of benzophenone and camphorquinone under UV and visible light. Upon irradiation at the corresponding wavelength, the excited photoinitiator abstracts hydrogen from HEMA or DMAEMA leading to the formation of initiating radicals. Depending on the concentration of inimers, type of the photoinitiator, and irradiation time, hyperbranched polymers with different branching densities and cross-linked polymers are formed. 
ISSN : 1022-1336 
Journal Name : MACROMOLECULAR RAPID COMMUNICATIONS 
Volume : 37 
Issue Number : 7 
Publishing Year : 1437 AH
2016 AD 
Article Type : Article 
Added Date : Sunday, August 13, 2017 

Researchers

Researcher Name (Arabic)Researcher Name (English)Researcher TypeDr GradeEmail
C AydoganAydogan, C Researcher  
M CiftciCiftci, M Researcher  
Y YagciYagci, Y Researcher  

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